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All I've got on the characters is that one is male and fights with the sword, while the other is female and prefers the bow. If you want, you can pick one and decide their name, appearance, personality, etc., and I'll take the other.
I think Zelda probably has the better potential out of the two. I'm sure Fallout could work too, but the fantasy world of Zelda is more free to the imagination, I think. I actually have a couple of characters for Zelda that I've had in my head for a while: Twins, a boy and a girl, of Link and Zelda's.
Here's an idea off the top of my head. After Zelda is kidnapped, Link goes on a journey to save her, but then he disappears. Impa, the caretaker of the twins, has a prophetic dream that the twins have been chosen by the gods as their next heroes. Then she'd have to try to protect the kids on their journey.
Impa could be treated as an NPC for both of us to share control of, and each of us can control one of the twins. When one's character is being punished, the other can take over primary control of Impa.